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For an overview of our recent publications, see the list below.
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| Sep 2003 | Affordable asymmetric olefin hydrogenation using monodentate phosphoramidites |
André de Vries, Jeroen Boogers, Michel van den Berg, Diego Peña, Adriaan Minnaard, Ben Feringa, Johannes de Vries
Pharmachem 2003, 9, 33-36
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| Sep 2003 | Chiral Hydroperoxides as Oxygen Source in the Catalytic Stereoselective Epoxidation of Allylic Alcohols by Sandwich-Type Polyoxometalates: Control of Enantioselectivity through a Metal-Coordinated Template |
Adam, Waldemar; Alsters, Paul L.; Neumann, Ronny; Saha-Moeller, Chantu R.; Seebach, Dieter; Beck, Albert K.; Zhang, Rui.
Journal of Organic Chemistry 2003, 68(21), 8222-8231
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| Sep 2003 | Intramolecular Staudinger Ligation: A Powerful Ring-Closure Method To Form Medium-Sized Lactams |
O. David, W.J.N. Meesters, H. Bieräugel, H.E. Schoemaker, H. Hiemstra and J.H. van Maarseveen
Angew. Chem. Int. Ed. 2003, 42, 4373-4375
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| Sep 2003 | Resolution of (R,S)-phenylglycinonitrile by penicillin acylase-catalyzed acylation in aqueous medium |
G.G. Chilov, H.M. Moody, W.H.J. Boesten, V.K. Svedas
Tetrahedron Asymmetry 2003, 14, 2613-2617
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| Aug 2003 | Nickel Catalyzed Cross-Coupling and Amination Reactions of Aryl Nitriles |
Miller, Joseph A.; Dankwardt, John W.; Penney, Jonathan M.
Synthesis 2003, 11, 1643
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| Jul 2003 | Dutch Resolution: Separation of Enantiomers with Families of Resolving Agents. A Status Report. |
R.M. M. Kellogg, J.W. Nieuwenhuijzen, K. Pouwer, T.R. Vries, Q.B. Broxterman, R.F.P. Grimbergen, B. Kaptein, R.M. La Crois, E. de Wever, A.C. van der Laan, K. Zwaagstra
Synthesis2003, 1626-1638
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| Jul 2003 | Quantitative Correlation of Solvent Polarity with the alpha-/3 10-Helix Equilibrium: A Heptapeptide Behaves as a Solvent-Driven Molecular Spring |
Paolo Pengo, Lucia Pasquato, Stefano Moro, Alessandro Brigo, Federico Fogolari, Quirinus B. Broxterman, Bernard Kaptein, Paolo Scrimin
Angew. Chem.Int. Ed, 2003, 42, 3388-3392
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| Jun 2003 | Vanadium Chloroperoxidase as a Catalyst for Hydrogen Peroxide Disproportionation to Singlet Oxygen in Mildly Acidic Aqueous Environment |
Rokus Renirie, Christel Pierlot, Jean-Marie Aubry, Aloysius F. Hartog, Hans E. Schoemaker, Paul L. Alsters, Ron Wever
Adv. Synth. Catal. 2003, 345, 849-858
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| Apr 2003 | Novel Reductive Amination of Nitriles: An Efficient Route to 5-Hydroxypiperidone-Derived N,N-Acetals |
Mandy K. S. Vink, Christien A. Schortinghuis, Antonina Mackova-Zabelinskaja, Martin Fechter, Peter Pöchlauer, A. Marianne C. F. Castelijns, Jan H. van Maarseveen, Henk Hiemstra, Herfried Griengl, Hans E. Schoemaker, Floris P. J. T. Rutjes
Adv. Synth. Catal. 2003, 345(4), 483-487
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| Apr 2003 | Rhodium-catalysed asymmetric hydroformylation of unsaturated nitriles |
M.M.H. Lambers-Verstappen and J.G. de Vries
Adv. Synth. Catal. 2003, 345(4), 478-482
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| Apr 2003 | A Water-Soluble and "Self-Assembled" Polyoxometalate as a Recyclable Catalyst for Oxidation of Alcohols in Water with Hydrogen Peroxide |
Sloboda-Rozner, Dorit; Alsters, Paul L.; Neumann, Ronny.
Journal of the American Chemical Society 2003, 125(18), 5280-5281
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| Apr 2003 | Selective oxidation of alcohols to carbonyl compounds and carboxylic acids with platinum group metal catalysts |
Anderson, Ross; Griffin, Ken; Johnston, Peter; Alsters, Paul L..
Advanced Synthesis & Catalysis 2003, 345(4), 517-523.
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| Apr 2003 | Application of monodentate secondary phosphine oxides, a new class of chiral ligands, in Ir(I)-catalyzed asymmetric imine hydrogenation |
Jiang, X.-b.; Minnaard, A. J.; Hessen, B.; Feringa, B. L.; Duchateau, A. L. L.; Andrien, J. G. O.; Boogers, J. A. F.; de Vries, J. G.
Org. Letters 2003, 5, 1503-1506
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| Mar 2003 | Rhodium-Catalysed Asymmetric Hydroformylation of Unsaturated Nitriles |
M.M.H. Lambers-Verstappen and J.G. de Vries
Adv. Synth. Catal. 2003, 345, 478-482
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| Mar 2003 | Improving conversion and enantioselectivity in hydrogenation by combining different monodentate phosphoramidites; a new combinatorial approach in asymmetric catalysis |
D. Peña , A.J. Minnaard , J.A.F. Boogers , A.H.M. de Vries, J.G. de Vries and B.L. Feringa
Org. Biomol. Chem. 2003, 1(7), 1087 - 1089.
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| Mar 2003 | The power of high-throughput experimentation in homogeneous catalysis research for fine chemicals |
J.G. de Vries and A.H.M. de Vries
Eur. J. Org. Chem. 2003, 799-811
Cover picture
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| Mar 2003 | Dispelling the Myths: Biocatalysis in Industrial Synthesis |
H. Schoemaker, D. Mink, M. Wubbolts
Science 2003, 299, 1694-1697
Download the publication at the Science website:
(please, before downloading the publication: check the URL. It should be:
http://www.dsm.com/en_US/html/dpp/publications.htm.
If you find a "5" behind "www", please remove it.)
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| Feb 2003 | Nickel catalyzed cross-coupling of modified alkyl and alkenyl Grignard reagents with aryl- and heteroaryl nitriles: activation of the C–CN bond |
Joseph A. Miller and John W. Dankwardt
Tetrahedron Lett. 2003, 44, 1907
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| Feb 2003 | Highly sustainable catalytic dehydrogenation of alcohols with evolution of hydrogen gas |
G. B. W. L. Ligthart, R. H. Meijer, M. P. J. Donners, J. Meuldijk, J. A. J. M. Vekemans and L. A. Hulshof
Tetrahedron Letters, 2003, 44 (7), 1507-1509
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| Feb 2003 | Folding of Peptides Characterized by c3Val, a Highly Constrained Cyclopropane Analogue of Valine |
C. Peggion, F. Formaggio, M. Crisma, C. Toniolo, A.I. Jiménez, C. Cativiela, B. Kaptein, Q.B. Broxterman, M. Saviano and E. Benedetti.
Biopolymers 2003, 68, 178-191
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| Jan 2003 | General procedure for the preparation of alkylzinc reagents from unactivated alkyl bromides and chlorides |
Shouqun Huo
Org. Lett. 2003, 5, 423
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| Jan 2003 | Monodentate phosphoramidites. A breakthrough in rhodium catalysed asymmetric hydrogenation of olefins |
M. van den Berg, A. J. Minnaard, R. M. Haak, M. Leeman, E. P. Schudde, A. Meetsma, B. L. Feringa, A.H.M. de Vries, C. E. P. Maljaars, C. E. Willans, David Hyett, J.A.F. Boogers, H.J.W. Henderickx, J.G. de Vries
Adv. Synth. Catal. 2003, 345(1-2), 308-322
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| ___ | The listed presentations present an overview of DSM Fine Chemicals' scientific activities |
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| 1. | Evidence for generation of singlet oxygen from ozone |
Singlet oxygen is the lowest excited state of molecular oxygen with unique properties with respect to chemical selectivity.
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| 2. | Transition Metal Catalysed Benzylic Oxidations with Ozone |
Combined use of a transition metal and ozone results in an industrially attractive and very powerful process.
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| 3. | Chromium Catalyzed Oxidations of Alcohols with Sodium Periodate |
An industrially attractive and very powerful alcohol oxidation process.
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| 4. | Retro-Strecker Reaction used for the Production of 4-Hydroxybenzaldehyde |
A new technology to prepare aldehydes from amino acids.
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| 5. | Production of Pyridinecarboxylic acids via aqueous ozonolysis on industrial scale |
Substituted pyridinecarboxylic acids are versatile intermediates for agrochemicals and pharmaceuticals.
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