When exposed to heat and flames, melamine decomposes, absorbing heat and
causing a cooling effect. And since it also gives off nitrogen during
decomposition, this helps to starve the fire of oxygen. This inhibits the
spread of flames and the generation of toxic smoke.
Coatings
When melamine-based flame-retardant (intumescent)
coatings are exposed to fire, they degrade to form a char or insulated surface
as the melamine decomposes. The result is that the substrate material beneath
the char surface is protected from the heat for a certain amount of time.
Environmental benefits
Melamine-based flame-retardants are more
environmentally benign than conventional halogen-based flame-retardants.