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Water absorption and dimensional stability of Akulon polyamides

As with all polyamides, Akulon absorbs moisture reversibly from the environment until it reaches an equilibrium. PA6 absorbs more water than PA66, especially under high humidity conditions, however the resulting dimensional change is the same as PA66.  Glass fiber reinforced and glass/mineral filled materials reduce moisture absorption to a level sufficient for most applications. Akulon, even reinforced and filled grades, are not recommended for programs requiring very tight tolerances.  Consult with a DSM Engineering Plastics specialist for guidance on use of Akulon grades for these types of applications.

Absorbed water acts as a plasticizer reducing strength and stiffness at low temperatures, but increasing toughness.  Although at room temperature moisture uptake reduces the stiffness and strength of PA6 more than for PA66, the difference is not significant. This is particularly true in applications that operate in environments above 100°C (212°F) since any moisture absorbed is rapidly desorbed under these conditions. For critical designs at elevated temperatures the influence of water absorption on mechanical properties can be ignored. Note however that the temperature effects on properties need to be considered in those cases.

Moisture content vs relative humidity.

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Dimensional change (%) of polyamide grades as function of moisture uptake.

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